Bis(tetrapropylammonium) di-μ3-iodido-di-μ2-iodido-diiodidodipyridinetetracopper(I)

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منابع مشابه

Bis(tetra­propyl­ammonium) di-μ3-iodido-di-μ2-iodido-diiodidodi­pyridine­tetra­copper(I)

The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro-iodic acid, tetra-propyl-ammonium iodide and pyridine under hydro-thermal conditions. In the centrosymmetric Cu(4)I(6) (2-) anion, one Cu site is in a trigonal-planar coordination while the second Cu site, which is only partially occupied [site occupancy of 0.596...

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Bis(μ-di-2-pyridyl disulfide-κ3 N,S:N′)di-μ3-iodido-di-μ2-iodido-tetra­copper(I)

In the centrosymmetric tetra-nuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetra-hedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu...

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catena-Poly[[bis­(μ2-1,4,7,10,13,16-hexa­oxacyclo­octa­deca­ne)dipotassium]-μ2-iodido-(iodidocadmium)-di-μ2-iodido-(iodidocadmium)-μ2-iodido]

The reaction of CdCl(2), 18-crown-6 and KI in water yields the title coordination polymer, [{K(C(12)H(24)O(6))}(2)Cd(2)I(6)](n). The potassium ion lies approximately in the plane of the crown ether, coordinated by all six crown ether O atoms and also by an iodide anion bound to a cadmium atom. A C atom of the crown ether is disordered over two positions with site occupancies of 0.77 (2) and 0.2...

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Di-μ3-iodido-diiodidobis(μ2-4′-phenyl-2,2′:6′,2′′-terpyridine)tetra­copper(I)

The title complex, [Cu(4)I(4)(C(21)H(15)N(3))(2)], lies on an inversion centre located at the centroid of a four-membered ring formed by one of the crystallographically independent Cu(I) ions and a triply bridging iodide ligand. The 2,2':6',2''-terpyridine (phterpy) ligand chelates each of the independent Cu(I) centres in a bidentate fashion, with the N atom of the central pyridyl ring bridging...

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Crystal structure of tris­[μ2-bis­(di­phenyl­phosphan­yl)methane-κ2 P:P′]di-μ3-iodido-tris­ilver(I) iodide–N-phenyl­thio­urea (1/1)

The title complex, [Ag3I2(C25H22P2)3]I·C7H8N2S, comprises a trinuclear [Ag3I2(C25H22P2)3](+) unit, an I(-) anion and one N,N'-phenyl-thio-urea mol-ecule (ptu). Two μ3-bridging I(-) anions are linked by three Ag(I) ions, leading to the formation of a dicapped triangular motif with Ag⋯Ag separations in the range 3.0823 (5)-3.2999 (5) Å. Each Ag(I) atom exhibits a distorted tetra-hedral geometry, ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810010202